Metallic bonding: OCR A A-level Chemistry

Explain metallic properties using cations and delocalised electrons.

OCR A · Bonding · Notes and practice

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Metallic bonding

1 practice questions
Learning goalExplain metallic properties using cations and delocalised electrons.

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A metal contains a giant lattice of positive ions surrounded by delocalised electrons. 'Delocalised' means the electrons are not restricted to one atom or one bond.

The attraction between the positive ions and these electrons holds the metal together. Strong attractions often give metals high melting and boiling points.

The delocalised electrons can move and carry charge in both solid and liquid metals. The positive ions do not travel through the solid to conduct electricity.

Metals do not normally dissolve as intact metallic lattices in molecular solvents. A metal reacting with a substance is a different process.

Metallic bonding
Strong electrostatic attraction between positive metal ions and delocalised electrons.
EXAM TRAPName the mobile charge carriers as delocalised electrons. The positive ions are fixed in a solid metal.

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Work on paper. Attempt each question before opening its answer. These are original CrackingChem questions, written in OCR A style.

Exam-style question 20

Magnesium has a giant metallic lattice.

(a) Describe the particles and attraction in metallic magnesium. [2 marks]

(b) Explain why magnesium conducts electricity as both a solid and a liquid. [2 marks]

(c) Explain why magnesium has a relatively high melting point. [2 marks]

Total: 6 marks

Show answer & marking points

(a) Magnesium contains positive metal ions and delocalised electrons [1] with strong electrostatic attraction between them [1]. [2]

(b) Delocalised electrons are mobile in both solid and liquid magnesium [1] and carry electrical charge [1]. [2]

(c) Strong electrostatic attractions act throughout the giant lattice [1], so much energy is needed to overcome them [1]. [2]

✓ DONE WHENYou explain metallic conductivity in both states and link melting to electrostatic attraction.

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